Synthesis of La1-xSrxAlO3 Perovskites by Reverse Strike Co-Precipitation Method and Its Soot Oxidation Activity

Authors

  • Harshini Dasari Department of Chemical Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Karnataka, 576104, INDIA
  • Naveen lAshok Yaranal Department of Chemical Engineering, Indian Institute of Technology, Guwahati, Assam, 781039, INDIA
  • Satya deepika Neelapala Department of Chemical Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Karnataka, 576104, INDIA
Abstract:

La1-xSrxAlO3 (x=0 to 0.4) perovskite materials were synthesized by the reverse strike co-precipitation method and their soot oxidation activity was evaluated. All the catalysts synthesized were characterized using XRD, BET specific surface area, FESEM and XPS techniques. As analyzed by XRD, La1-xSrxAlO3 perovskite from x=0 to 0.35 showed the formation of the rhombohedralphase, while for La0.6Sr0.4AlO3 sample the secondary phases SrO, La2O3, and Al2O3 were also noticed. Sr-doped samples exhibited higher BET specific surface area when compared to pure LaAlO3. FESEM analysis showed that there is a change in morphology upon doping of Sr into LaAlO3 lattice. The O1s spectra observed from XPS analysis showed that the La0.75Sr0.25AlO3 sample contained higher amounts of adsorbed oxygen. La, Sr, and Al existed in +3, +2 and +3 oxidation states respectively in all the synthesized samples as confirmed by XPS. Soot oxidation activity tests showed that La0.75Sr0.25AlO3 exhibited higher catalytic activity relative to other catalysts due to the enhanced amount of reactive adsorbed oxygen species.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Synthesis and characterization of SnO2 nanoparticles by Co-Precipitation method

Tin oxide (SnO2)nanoparticles were synthesized by co-precipitation method and the synthesized nanoparticles were annealed at different temperatures for characterization. The powders were investigated with X-ray diffraction, scanning electron microscopy and optical spectroscopy. The structural characterization was carried out by X-ray diffraction which confirms the crystalline nature ...

full text

Synthesis of Nano-Structured La0.6Sr0.4Co0.2Fe0.8O3 Perovskite by Co-Precipitation Method

Nano-structured lanthanum strontium cobalt ferrite, La0.6Sr0.4Co0.2Fe0.8O3 (LSCF), was successfully synthesized via co-precipitation method using metal nitrates as starting materials. Effects of precipitating agent and calcination temperature on the phase composition and morphology of synthesized powders were systematically studied using X-ray diffraction (XRD) and field emission scanning elect...

full text

SYNTHESIS OF AL2O3-NI COMPOSITE POWDERS BY CO-PRECIPITATION METHOD

The synthesis of micro-sized, uniformly distributed Al2O3-15Vol% Ni powders were studied through three step co-precipitation of hydroxides mixtures from proper solution, calcination at air atmosphere and final step of calcined powders in a carbon bed. Al and Ni hydroxide and amorphous phase were first obtained from their salt’s solutions through chemical co-precipitation method by adjusti...

full text

Reverse chemical co-precipitation: An effective method for synthesis of BiFeO3 nanoparticles

The reverse co-precipitation method was used for synthesis of the pure phase multiferroic BiFeO3 (BFO) nanoparticles. Influence of different pH values on the microstructure and magnetic properties of the BFO nanopowders was investigated. Thermogravimetric-differential thermal analysis (TG-DTA) technique indicated that the optimal temperature for calcination is 550°C. The phase formation and the...

full text

Synthesis and Characterization of α-Fe2O3 Nanoparticles by Simple Co-Precipitation Method

In the past decade, magnetic nanomaterials have attracted much attention due to their physical properties and technological applications. In this work, α-Fe2O3 nanoparticles were first synthesized via a simple co-precipitation method using iron chloride hexahydrate (FeCl3.6H2O) as precursor and ammonia solution as precipitator. The samples we...

full text

extraction and characterization of allium irancum plant extract and its application in the green synthesis of silver nano particles and oxidation of thiocarbony1 compounds

سنتز سبز نانوذرات فلزی (nps) درسالهای اخیر توجه بسیارزیادی را به خود جلب کرده است. زیرا این پروتوکل کم هزینه وسازگار با محیط زیست از روش های استاندارد سنتز. در این پایان نامه ما گزارش میکنیم یک روش ساده و سازگار با محیط زیست برای سنتز نانوذرات نقره با استفاده از محلول آبی عصاره گیاه allium iranicum به عنوان یک عامل کاهش دهنده ی طبیعی. نانو ذرات نقره مشخص شد با استفاده از تکنیک های uv-visible، x...

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 38  issue 4

pages  69- 77

publication date 2019-08-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023